You can use the following query on your App-V 5.0 reporting server database (AppVReporting) to get application usage information for which users ran which software on which systems and when.
select distinct username, host_name, app_name, start_time from dbo.ApplicationUsage APPU join dbo.ClientInformation CLIINFO on APPU.host_id=CLIINFO.host_id order by start_time desc
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